Cost-effective, high-capacity, and cyclable lithium-ion battery cathodes

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Cost-effective, high-capacity, and cyclable lithium-ion battery cathodes
Fuel CellsEnergy And ResourcesAlternative Fuels
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Charge-recharge cycling of lithium-superrich iron oxide, a cost-effective and high-capacity cathode for new-generation lithium-ion batteries, can be greatly improved by doping with readily available mineral elements.

The energy capacity and charge-recharge cycling of lithium-iron-oxide, a cost-effective cathode material for rechargeable lithium-ion batteries, is improved by adding small amounts of abundant elements.

A crucial chemical aspect of the enhancement proved to be the formation of strong 'covalent' bonds between the dopant and oxygen atoms within the structure. These bonds hold atoms together when electrons are shared between the atoms, rather than the 'ionic' interaction between positive and negatively charged ions.

"We will continue to develop these new insights, hoping to make a significant contribution to the advances in battery technology that will be crucial if electric power is to widely replace fossil fuel use, as required by global efforts to combat climate change," Kobayashi concludes.

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