Rory McIlroy will get his 10th attempt to complete the career Grand Slam under way at 15:42 BST on Thursday when the Masters starts at Augusta National.
The Northern Irishman plays with the only man ranked higher than him in the world, 2022 champion Scottie Scheffler, and fellow American Xander Schauffele.
Defending champion Jon Rahm is out in the group before at 15:30, alongside England's Matt Fitzpatrick.Record six-time winner Jack Nicklaus, three-time champion Gary Player and twice winner Tom Watson will hit the ceremonial opening tee shots before South Africa's Erik Van Rooyen is first to tee off at 13:00 .
The final group of 2020 Masters champion Dustin Johnson, 2021 Open winner Collin Morikawa and England's Tommy Fleetwood will get under way six hours later.
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