Physicists explain--and eliminate--unknown force dragging against water droplets on superhydrophobic surfaces

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Physicists explain--and eliminate--unknown force dragging against water droplets on superhydrophobic surfaces
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Researchers adapt a novel force measurement technique to uncover the previously unidentified physics at play at the thin air-film gap between water droplets and superhydrophobic surfaces.

Microscopic chasms forming a sea of conical jagged peaks stipple the surface of a material called black silicon. While it's commonly found in solar cell tech, black silicon also moonlights as a tool for studying the physics of how water droplets behave.

Aalto University Assistant Professor Matilda Backholm is the first author of the paper that details these findings, published on April 15 in the journalShe conducted this during her time as a postdoctoral researcher in Professor Robin Ras's Soft Matter and Wetting group in the Department of Applied Physics.

Black silicon exploits the specific surface tension of water to minimize the contact between the droplet and the surface. Cones etched onto the substrate make the water droplets glide on an air-film gap, known as a plastron. But in a counterintuitive twist, the very mechanism that enables hydrophobic surfaces to deflect water droplets also leads to the shearing effect outlined in Backholm's paper.

'This work builds upon the wealth of expertise from the Soft Matter and Wetting research group on the subject of superhydrophobic surfaces. Rarely does the opportunity emerge to fully explain the subtleties of the microscopic forces involved in wetting dynamics, but this paper accomplishes just that,' says Ras.Backholm adapted a unique micropipette measurement technique to gauge the forces acting against the water droplets.

Backholm expects these findings will further enable physicists and engineers to develop hydrophobic surfaces with better performance.Matilda Backholm, Tytti Kärki, Heikki A. Nurmi, Maja Vuckovac, Valtteri Turkki, Sakari Lepikko, Ville Jokinen, David Quéré, Jaakko V. I. Timonen, Robin H. A. Ras.Researchers have developed a superhydrophobic surface with a stable plastron that can last for months under water.

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