The favourites are knocked out in the fourth round by Miron Muslic's side
Seventeen-year-old midfielder Trey Nyoni was handed a start alongside fellow academy youngster James McConnell, while fellow U21s Isaac Mabaya and Trent Kone-Doherty also came off the bench.
That was one of just two shots on target Argyle managed all game, alongside 25 per cent possession, but they took advantage of a second-choice and second-rate Liverpool But under new boss Miron Muslic Plymouth have lost just two of their seven matches, and this result will inspire hope anew at Home Park.
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