Police say the man and woman are not thought to have suffered life-threatening injuries
The A6 Bakewell Road was briefly closed between the junction for the Arc Leisure Centre and the A615Derbyshire Police said officers were called at about 14:00 GMT on Monday, and found a car on its side on the A6 Bakewell Road.
Both in the vehicle were taken to Chesterfield Royal Hospital, the force said, with their injuries "not thought to be life-threatening". The road was closed between the Arc Leisure Centre and the junction with the A615, but has now reopened.
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