The bus and motorbike collided on Alison Road and Doncaster Avenue in Kensington about 3pm.
"NSW Ambulance paramedics treated the rider – a man believed to be in his 20s – before taking him to St Vincent's Hospital in a critical condition," police said in a statement.The man died in hospital a short time later.
"The bus driver - a 34-year-old woman - was uninjured and taken to Prince of Wales Hospital for mandatory testing," police said.
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