Met Office yellow weather warnings are in force, with disruption to travel and other activities possible.
BBC forecaster Sarah Keith-Lucas said that Tuesday night could be the coldest of the week and one of the coldest of the year, with lows of -10C possible in Scotland.
But the forecast for the middle of the week is less certain, with the arrival of warmer air from the Atlantic expected to create a "battleground" over the UK, she said. Earlier alerts issued by the UK Health Security Agency also remain in place. These warn that all of England is likely to experience cold weather for much of next week.
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